Back from work now. 24s refers to a battery with 24 cells series connected. With RC lipo packs from hobby king, you string 24 cells in series and you get 90-110v
Whatever you get, I suggest trying it out at 48v. See if the bike is in the get you killed class or not, can you stop at 30 mph, does it get the death wobbles, etc. Then if it's solid, a 72v 20 amp controller is going to get you to the next level without melting a kit motor intended for 800w or so.
To get into the above 40mph club takes a strong bike, at least 72v 40 amps, and really good brakes. Tires can be worn out in one day if you corner enough.
So it gets to be a bit of $$ for the fun. 30 mph can be done by most any bike. It's just that the cheap one will wear out fast.