You certainly can use a LiFePO4 as a starting battery. The largest benefit will be the weight reduction. The 4S2P (20Ah) PSI pack in my VW diesel weights just under 11 pounds while the Optima red top I used before lithium weighed 38 lbs, and the OEM size chunk of lead was closer to 45lbs. Lower weight and thus lower rolling resistance affects all phases of the drive.
As for other fuel economy numbers...beware of testimonials and the power of suggestion. One example:
http://ecomodder.com/blog/one-big-reason-not-to-trust-real-world-fuel-economy-testing/
One US lab that's certified to conduct government tests is Southwest Research Institute (SwRI) here in San Antonio. Here's an overview of their on-road testing:
http://www.swri.org/3pubs/BROCHURE/d08/FuelEcon/FuelEcon.htm Note some important points - test and control vehicles on the road at the same time, standardized fuel, weather monitoring, tyre pressure monitoring, vehicle weight standardization, and vehicle operators trained to perform standardized tests. (Note - multiple vehicles on the road - trained drivers - and none of them know which are the 'test vehicles' and which is 'control'...)
Fuel and oil testing done in lab conditions is conducted in accordance with internationally-recognized ASTM procedures. For example - to see how a new engine oil formulation affects fuel economy, it's run against standardized test oil. In order to conduct a valid test, the following parameters are accounted for: (From the ASTM:
http://www.astm.org/Standards/D6837.htm)
"This test method covers an engine test procedure for the measurement of the effects of automotive engine oils on the fuel economy of passenger cars and light-duty trucks with gross vehicle weight of 3856 kg or less. The tests are conducted on a dynamometer test stand using a specified spark-ignition engine with a displacement of 4.6-L. It applies to multiviscosity grade oils used in these applications."
(All tests are run on the same type of engine. Engines are completely rebuilt and run-in with a standard procedure before tests are run -- each test is run on identical equipment in a controlled environment with standardized fuel, a certified process, and as conducted by trained operators. This test protocol can measure effects of moving from 5W-20 to 0W-20 engine oil, for example, or petroleum to synthetic.)
Test Engine Configuration 6.2
Laboratory Ambient Conditions 6.3
Engine Speed and Torque Control 6.4
Dynamometer 6.4.1
Dynamometer Torque 6.4.2
Engine Cooling System 6.5
External Oil System 6.6
Fuel System 6.7
Fuel Flow Measurement 6.7.2
Fuel Temperature and Pressure Control to the Fuel Flowmeter 6.7.3
Fuel Temperature and Pressure Control to Engine Fuel Rail 6.7.4
Fuel Supply Pumps 6.7.5
Fuel Filtering 6.7.6
Engine Intake Air Supply 6.8
Intake Air Humidity 6.8.1
Intake Air Filtration 6.8.2
Intake Air Pressure Relief 6.8.3
Temperature Measurement 6.9
Thermocouple Location 6.9.5
AFR Determination 6.10
Exhaust and Exhaust Back Pressure Systems 6.11
Exhaust Manifolds 6.11.1
Laboratory Exhaust System 6.11.2
Exhaust Back Pressure 6.11.3
Pressure Measurement and Pressure Sensor
Locations 6.12
Engine Oil 6.12.2
Fuel to Fuel Flowmeter 6.12.3
Fuel to Engine Fuel Rail 6.12.4
Exhaust Back Pressure 6.12.5
Intake Air 6.12.6
Intake Manifold Vacuum/Absolute Pressure 6.12.7
Coolant Flow Differential Pressure 6.12.8
Crankcase Pressure 6.12.9
Engine Hardware and Related Apparatus 6.13
Test Engine Configuration 6.13.1
ECM/EEC (Engine Control) Module 6.13.2
Thermostat/Orifice Plate 6.13.3
Intake Manifold 6.13.4
Flywheel 6.13.5
Wiring Harnesses 6.13.6
EGR Block-Off Plate 6.13.7
Oil Pan 6.13.8
Oil Pump Screen and Pickup Tube 6.13.9
Idle Speed Control Solenoid (ISC) Block-Off Plate 6.13.10
Engine Water Pump 6.13.11
Thermostat Housing 6.13.12
Oil Filter Adapter 6.13.13
Fuel Rail 6.13.14
Miscellaneous Apparatus Related to Engine Operation 6.14
Timing Light 6.14.1
Reagents and Materials 7
Engine Oil 7.1
Test Fuel 7.2
Engine Coolant 7.3
Cleaning Materials 7.4
Preparation of Apparatus 8
Test Stand Preparation 8.2
Engine Preparation 9
Cleaning of Engine Parts 9.2
Engine Assembly Procedure 9.3
General Assembly Instructions 9.3.1
Bolt Torque Specifications 9.3.2
Sealing Compounds 9.3.3
Harmonic Balancer 9.3.5
Oil Pan 9.3.6
Intake Manifold 9.3.7
Camshaft Covers 9.3.8
Thermostat 9.3.9
Thermostat Housing 9.3.10
Coolant Inlet 9.3.11
Oil Filter Adapter 9.3.12
Dipstick Tube 9.3.13
Water Pump 9.3.14
Sensors, Switches, Valves, and Positioners 9.3.15
Ignition System 9.3.16
Fuel Injection System 9.3.17
Intake Air System 9.3.18
Engine Management System (Spark and Fuel Control) 9.3.19
Accessory Drive Units 9.3.20
Exhaust Manifolds 9.3.21
Engine Flywheel and Guards 9.3.22
Lifting of Assembled Engines 9.3.23
Engine Mounts 9.3.24
Calibration 10
Stand/Engine Calibration 10.1
Procedure 10.1.1
Reporting of Reference Results 10.1.2
Analysis of Reference/Calibration Oils 10.1.3
Instrument Calibration 10.2
Engine Torque Measurement System 10.2.1
Fuel Flow Measurement System 10.2.2
Coolant Flow Measurement System 10.2.3
Thermocouple and Temperature Measurement System 10.2.4
Humidity Measurement System 10.2.5
Other Instrumentation 10.2.6
Test Procedure 11
Preparation for Initial Start-up of New Engine 11.1
External Oil System 11.1.1
Flush Effectiveness Demonstration 11.1.2
Preparation for Oil Charge 11.1.3
Oil Charge for Coolant Flush 11.1.4
Engine Coolant Charge for Coolant Flush 11.1.5
Initial Engine Start-up 11.2
Coolant Flush 11.3
New Engine Break-In 11.4
Oil Charge for Break-In 11.4.2
Break-In Operating Conditions 11.4.3
Routine Test Operation 11.5
Start-Up and Shutdown Procedures 11.5.8
Flying Flush Oil Exchange Procedures 11.5.9
Test Operating Stages 11.5.10
Stabilization to Stage Conditions 11.5.11
Stabilized BSFC Measurement Cycle 11.5.12
Data Logging 11.5.13
BC Oil Flush Procedure for BC Oil Before Test
Oil 11.5.14
BSFC Measurement of BC Oil Before Test Oil 11.5.15
Test Oil Flush Procedure 11.5.16
Test Oil Aging 11.5.17
BSFC Measurement of Aged (Phase I) Test Oil 11.5.18
Aging Phase II 11.5.19
BSFC Measurement of Aged (Phase II) Test Oil 11.5.21
BC Oil Flush Procedure for BC Oil After Test Oil 11.5.22
BSFC Measurement for BC Oil After Test Oil 11.5.23
General Test Data Logging Forms 11.5.24
Diagnostic Review Procedures 11.5.25
Determination of Test Results 12
FEI1 and FEI2 Calculations 12.1
Final Test Report 13
Validity Statement 13.1
Report Format 13.2
Precision and Bias 15
Precision 15.1
Validity 15.2
Test Stand Calibration Status 15.2.1
Validity Interpretation of Deviant Operational Conditions 15.2.2
Bias 15.3
To generate meaningful numbers for fuel economy due to a battery swap, the tests should be run in this type of controlled environment with a double-blind protocol and trained staff -- not on a road with the vehicle operator (and battery shop owner...) behind the wheel. As you probably already know - one can significantly affect fuel economy simply by making tiny changes in driver behaviour. I can swing the fuel economy in my '97 VW Passat TDI between 0 and 52 MPG (hey - more than 6000 MPG down hill!) thru driver behaviour alone...
Testimonials are not science.
Andy