Hi scfoster, i have the same setup. I think 28S would leave you too little safety room... the FETs inside the adaptto are rated for 100v, and when your cells are fully charged they will be higher then 3.3v. When people on endless sphere advise not going above 22s, they are talking about lipo/NMC chemistry, which has a charged voltage of 4.2v per cell, so 22s is the highest you can go. Because your cells are 3.3v, you could go 24s or 22s. Your gt4000 is 3 turn, so is about 11.6kv, which means if you run 72v, you'll get 840rpm, which in a 24" wheel (wack a 3.5" tyre on the 17" rim of your gt4000, you'll love it) means you'll go 60mph full throttle. Thats will be your vanilla speed, before OVS. OVS will increase that speed, so if you were looking to go 60mph+ (if that was your plan, you'll be wanting that 3.5" tyre for stability!), 24s or 22s, maybe even 20s, combined with adapttos awesome OVS, will get you all the speed you need. What you'll start to find is that the battery and controller are no longer the limits to your speed, but the motor temperatures. The gt4000 is good for 4.5kw continuous, but if you want to go 60mph continuous you need to supply about 7000w+ to that motor!
Anyway hope this helps, if ive got any of these calculations wrong please someone correct me.