Yes. What you need to do though, is figure out what voltage your v power battery needs. It's very likely to be similar to a Ping,, that is,, a 16s lifepo4.
This would charge to about 58v. But it may be a 15s,, if so,, 58v will be a bit high charged for it.
Charge it with your 54.6v charger if that is what you have. Then see what the voltage of each cell is. If a 56.4v charge gets all your cells to 3.5v while the charger is still plugged in, green light on,, then you have a charger you can use fine. Your pack is 15s.
If you have a 16s pack, your cells will only charge to 3.4v each.
However,, an old v power pack,, known to be a turd,, it may have lots of cells that only charge to 2v or less, and much of the pack may be a door stop. lightly used or not,, if it sat for awhile,, it may have some dead cell groups in it.
Plug in and try,, If your charger is a 58v,, it won't overcharge it beyond what 15s lifepo4 can handle. Do it outside though, just in case.